In particular, the redox reaction of Cr(III)/Cr(II) was investigated by combining spectroscopy and electrochemistry in the same unit cell to obtain its formal potential, the number of electrons, and the diffusion coefficient of Cr(II). The molar absorption coefficients and molecular structures of the ions were obtained by UV–vis-NIR absorption spectroscopy (250–950 nm). The diffusion coefficients were obtained and compared in terms of both CV and CA results. The formal potentials and standard rate constants of the redox reactions were measured by CV results from both correlations and numerical fitting. In this study, CV was used to characterize redox reactions of Fe(II)/Fe(0), Ni(II)/Ni(0), Co(II)/Co(0), Cr(II)/Cr(0), and Cr(III)/Cr(II). Moreover, the obtained properties have not been applied to explain observed experimental phenomena to show their applicability and completeness. For this reason, the reversibility of the electrochemical systems according to the scan rates of CV has often been ignored. 24 The rate constants of redox reactions were rarely obtained. The spectroelectrochemical measurements were performed only for some elements such as Eu, 22 Sm, 23 and U. 21 However, few studies have explored electrochemical redox reactions at high temperature molten salts while simultaneously monitoring changes in oxidation state using absorption spectroscopy. investigated the possibility of separating Ni and Co in LiCl-KCl using chronopotentiometry (CA) and cyclic voltammetry (CV). ![]() 15– 20 In 2017, Park et al., examined redox behaviors of Zr, Sn, Cr, Fe, and Co in LiCl-KCl using W working electrodes to develop a Zircaloy-4 decontamination process. Some researchers have attempted to apply electrochemical methods for the metallic constituents of nuclear power plant components in LiCl-KCl. 12– 14 Therefore, the thermodynamic, kinetic, and spectroscopic behavior of reduction-oxidation reactions is significant to design and optimize the decontamination process. The electrode potential is controlled to selectively recover each component by depositing it on the surfaces of a metallic cathode. During electrorefining, the contaminated structural components are dissolved into a lithium chloride-potassium chloride (LiCl-KCl) electrolyte. 3, 5 This process was originally developed for recovering uranium from used nuclear fuel. 6– 11 The concept underlying the process can also be used as a decontamination option when radioactive contaminants exist at levels deeper than the surface oxide layers. 4, 5Īn electrorefining process using molten salt has been developed to treat and recycle nuclear materials in used nuclear fuel. 3 In addition, decontaminating the waste can change waste categories from intermediate level waste to low level waste. Such radioactive waste must be decontaminated to reduce the volume of final waste as well as to meet the waste acceptance criteria of the final repository. In particular, radioactive isotopes are distributed in the volume of the reactor internals and pressure vessels made of steel alloys because of neutron activation reactions. ![]() 1, 2 Structural components containing these metallic elements are activated in volume or contaminated on surfaces. ![]() Radioactive metallic waste produced from nuclear power plants commonly contains Cr, Fe, and Ni as alloying constituents and Co as an impurity. The findings of this study will be directly used for designing a decontamination process to produce acceptable waste forms and reduce waste volume. The obtained reaction properties were used in the numerical modeling of the ECE reaction in a Ni and Co binary system to reproduce the experimental results of CV, revealing the presence of chemical reaction. In particular, the redox reaction of Cr(III)/Cr(II) was investigated by chronoabsorptometry to obtain its formal potential, the number of electrons, and the diffusion coefficient of Cr(II). UV–vis-NIR absorption spectroscopy of the metallic constituents was performed to derive molar absorption coefficients and molecular structures in molten salt media. The order of the diffusion coefficients was 10 –5 cm 2 s −1, which agrees with the existing data and the standard rate constants showed similar values with the order of 10 –3 cm s −1 between experimental correlations and numerical fitting. Cyclic voltammetry combined with numerical fitting was used to obtain the formal potentials, standard rate constants, and diffusion coefficients of redox reactions, Cr(II)/Cr, Fe(II)/Fe(0), Co(II)/Co(0), and Ni(II)/Ni(0), in LiCl-KCl at 773 K. This study examines the thermodynamic, kinetic, and spectroscopic behaviors of Cr, Fe, Co, and Ni to lay the foundation to develop an electrochemical decontamination process for radioactive metallic wastes.
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The dredge is similar to a small pontoon boat. There is no damage to the shoreline or tracks to be repaired. The launching and loading are more like a boat than a conventional dredge or excavator. Mobilization costs are a fraction of a typical six-inch dredge. With a wet weight of around 4,000 pounds, it is a very lightweight portable dredge, with a low cost of mobilization, and a small environmental footprint. The dredge measures just over 22′ long and 6′ wide and is less than 6′ tall. Our sediment removal system is comprised of a small dredge manufactured domestically. Each dino dredge rental equipment may vary slightly from the overview. It will increase your property value, and prevent the need for expensive dredging.Below is a general overview of the sediment removal systems we use for dino dredge rentals. Take care of it with some of the approaches recommended above. In the event that you have started to accumulate some muck, Sludge Fighter Pellets will work to break them down so that you won't end up with a problem that is impossible to solve other than by dredging.ĭon't make a bigger problem for yourself by neglecting your pond. Pond bacteria and Sludge Fighter Pellets are a great way to combat algae and muck in the short term, while still maintaining a healthy ecosystem.īoth of these solutions are completely natural, and promote the health of the pond (compared to chemicals that kill algae, but also harm the pond).īacteria works along with the aeration to break down all of the nutrients in the water that create algae growth. This prevents muck from settling and creating the need for dredging. This way (in the event that they are not all broken down right away) the oxygen-rich water column can do its work over time. No muck = no dredging.īenefit #2: An efficient, effective aeration system will induce enough mixing of the water to keep the sediment / muck particles suspended in the water column. Healthy pond ecosystems break down algae and debris instead of letting them turn into muck. This is the step that pond owners with foresight will take in order to secure a healthy, sustainable pond ecosystem for years to come.īenefit #1: Aerating your pond allows for a healthy ecosystem to take hold. Pond aeration is one of the best ways to guard against the need to dredge. The simple act of paying attention to your pond, managing it, and taking the necessary actions can be the difference between enjoying a relaxing pond atmosphere and shelling out the cash for dredging. Clean, healthy ponds can increase property value by up to 20%! Whereas dirty ponds can end up decreasing that property value by 10-15%. Give it the care it needs to become an asset to your property. What happens if you ignore your garden? Or your yard? Or your furnace? Exactly. If you ignore it, you'll pay the price down the line. )Ī pond is like any other feature on your property - it must be taken care of. How can you avoid the need to dredge your pond? (And avoid spending all the money that comes along with that process. ![]() Don't bother looking for wildlife or fish, because they won't be able to survive. In this event, your pond becomes a cesspool full of algae and unpleasant odors. As a result, pond muck continues to build upon itself until a pond that was originally 8 feet deep is all of a sudden just 2 feet deep. Ponds reach this point from years pond chemical treatments, algae blooms, and/or neglect. Pond dredging sometimes becomes necessary when pond depth becomes too shallow for the pond to be self-sustaining. One more thing that's always the same: Dredging your pond is very expensive. This process can be done in a couple different ways, but each process has the same end goal: Pond dredging in Kansas, OK is the process by which pond muck, sediment, and sludge that has built up over time is removed by a machine. Language difficulties arise a common language should be used for navigational purposes, and that In 1973, the Maritime Safety Committee agreed, at its twenty-seventh session that where The vessel, the people on board and the environment. ![]() Languages, since problems of communication may cause misunderstandings leading to dangers to The increasing number of internationally trading vessels with crews speaking many different This is of particular importance in the light of There is a need to standardize the language used. RECOMMENDS Governments to give the IMO Standard Marine Communication Phrases a wide circulation to all prospective users and all maritime education authorities, in order to support compliance with the standards of competence as required by table A-II/1 of the STCW Code Īs navigational and safety communications from ship to shore and vice versa, from ship to ship,Īnd on board ship must be precise, simple and unambiguous so as to avo id confusion and error, AUTHORIZES the Maritime Safety Committee to keep the IMO Standard Marine Communication Phrases under review and to amend them when necessary in accordance with the procedure set out in Annex 2 to the present resolution ģ. ADOPTS the IMO Standard Marine Communication Phrases set out in Annex 1 to the present resolution Ģ. HAVING CONSIDERED the recommendations of the Maritime Safety Committee at its sixty-eighth and seventy- fourth sessions,ġ. RECOGNIZING ALSO the wide use of the English language for international navigational communications and the need to assist maritime training institutions to meet the objectives of safe operations of ships and enhanced navigational safety through, inter alia, the standardization of language and terminology used, RECOGNIZING that the standardization of language and terminology used in such communications would assist the safe operation of ships and contribute to greater safety of navigation, RECALLING FURTHER the provisions of regulation V/14.4 of the International Convention for the Safety of Life at Sea, 1974, requiring that on all ships to which chapter I thereof applies, English shall be used on the bridge as the working language for bridge-to-bridge and bridge-to-shore safety communications as well as for communications on board between the pilot and bridge watchkeeping personnel unless those directly involved in the communications speak a common language other than English, ![]() RECALLING ALSO resolution A.380(X) by which it adopted the Standard Marine Navigational Vocabulary, RECALLING Article 15(j) of the Convention on the International Maritime Organization concerning the functions of the Assembly in relation to regulations and guidelines concerning maritime safety,
The good thing about this remote desktop app is that it supports all popular desktop and mobile OS like Windows, macOS, Android, iOS, and Amazon Fire. It lets you do almost anything on a remote desktop like providing remote assistance, file sharing, accessing installed programs, playing games, etc. Splashtop is one of the most popular remote desktop apps out there. Pros: RealVNC is cross-platform and the connection between your systems is encrypted.Ĭons: The free version of RealVNC only offers basic functionality like viewing and controlling the remote system. RealVNC works on VNC (Virtual Network Computing) protocol, and the connection between systems is much more stable than when using the TeamViewer which is a plus. But, you still need to install the server and client applications as needed. However, it is much easier to use than TightVNC. RealVNC works a lot like TightVNC and allows you to connect and control remote Windows 10 and 11 computers. ![]() So no real cons as of now during our testing. And so is using the app to control your PC remotely.Ĭons: Sometimes, it lags if you are facing network issues but that’s true for any remote assistance software. Pros: The setup process is really easy and quick. Other features include file transfer, privacy mode, and remote printing. One of the better alternatives to TeamViewer app. It is completely free for personal usage without any ads but has plans for commercial users.ĪnyDesk plans begin at $11 for individual users and $14.99 for teams if you are running a business providing remote assistance with unattended access to customers. It offers Military-grade TLS 1.2 security and 256-bit AES transport encryption in a lightweight client that’s pretty fast. In fact, it even works on obscure ones like Raspberry Pi, FreeBSD, Linux, and ChromeOS. AnydeskĪs the name suggests, AnyDesk works on popular platforms be it Windows, macOS, Android, and iPhone. This simply means that you can use it to connect to other computers but others cannot connect to your computer as long as you are using the Home version. Pros: Free, powerful, highly customizable, and comes built-in on Windows 10 and 11.Ĭons: The Home version of Windows doesn’t have the server component for the Remote Desktop. Of course, you can access all your files and can even perform almost any Windows troubleshooting on the remote desktop. In Windows 10 and 11, you get a free remote access software called Remote Desktop Connection that enables you to quickly connect to any Windows system with just a few clicks. If you are running a Windows PC and want to remotely access a Windows PC, then you don’t have to download a 3rd party application. It supports almost all popular operating systems.Ĭons: They have a 5GB file transfer limit in the paid edition. Pros: Zoho Assist offers cloud-based unattended remote assistance. They also offer unattended access which means you can access your work computer from anywhere in the world by login in remotely. They have white-label plans for rebranding and custom domain solutions so you can start your own remote assistance company. That means technicians don’t have to install the app and can offer assistance on demand. It offers TLS 1.2 and AES 256-bit encryption while being cloud-based. Interestingly, Zoho has another remote access software called Assist. The UI can be a bit challenging for novice and first-time users. Supports video and voice chat, detailed reports, file transfers, and record sessions for future support and troubleshooting. Like TeamViewer, you can control systems remotely and transfer files, and also impose user-level restrictions. More suitable for IT admins who are overseeing a vast number of computers located across the globe and need to provide remote assistance to them. ![]() ManageEngine, from Zoho, offers a HIPPA-compliant remote desktop manager for enterprise users called Remote Access Plus. There may be others but for most home and even enterprise users, this should suffice. ![]() These are some of the best TeamViewer alternatives that we tested and used. Odds as of September 8 Sportsbook NFL Rushing TD Leader Best Bet: Derrick Henry (+600) Player to lead NFL in rushing Touchdowns Player Join A Top NFL Sportsbook Today! NFL Rushing TD Leader Odds To get Chubb at +900 seems like incredible value that shouldn’t be missed. Without an established starter calling plays, I bet the Browns double down on that running game and hand the ball to Chubb more frequently than they did in 2021 when he had 228 attempts. ![]() And that’s when they had a recognized starting QB in Baker Mayfield. ![]() The Browns finished fourth in the NFL in total rushing yards (2,471) in 2021. Not to mention Cleveland likes to rush the ball. Brissett has never thrown for more than 3,100 yards in a full season as QB. The Cleveland Browns will start Jacoby Brissett at QB for most of the season as Deshaun Watson serves his 11-game suspension. Sportsbook NFL Rushing Yards Best Bet: Nick Chubb (+900) Putting $100 on Henry to take back his rushing yards crown would net you a $500 profit if he does. He could have easily retained his rushing yards crown had he been healthy. Pace that out over 17 games and Henry was looking at roughly 1,990 yards on the ground. In 2021, despite a broken foot that cost him roughly half the season, he finished ninth in the league with 937 rushing yards. In 2019, he put up 1,540 yards and in 2020 he was the only player to rush for 2,000-plus yards. Henry is a two-time rushing yards leader in the NFL. Getting Taylor at +400 would return $400 on a winning $100 bet. Relying on Taylor to eat up as many yards as possible is definitely going to be the Colts’ strategy this season. The Colts’ starting QB for the season is 37-year-old Matt Ryan, who threw for 3,968 yards last season, his lowest total since 2010. There’s no reason to suggest Taylor will regress in 2022. ![]() That was an incredible 552 yards better than Nick Chubb’s 1,259 yards in second place. Taylor led the league in carries in 2021 with 332 and averaged 5.45 yards per attempt on his way to an NFL-best 1,811 yards. Join A Top NFL Sportsbook Today! 2022 NFL Rushing Leader Odds Favorites Jonathan Taylor (+400) ![]() Player to lead NFL in rushing yards Player Here’s a breakdown of 2022 NFL rushing yards leader and rushing TD leader odds with some of our favorite picks: 2022 NFL Rushing Yards Leader Odds Derrick Henry ( Tennessee Titans) is second on the oddsboard at +500 and Nick Chubb ( Cleveland Browns) sits third at +900. Taylor is the early favorite to repeat as the rushing yards leader in 2022 with odds at +400 per sportsbook Sportsbook. Over 70 percent of that production came through the play of running back Jonathan Taylor, who topped the NFL with 1,811 rushing yards. The Colts were right behind the Eagles with 2,540 rushing yards last year. The Eagles ran the ball for a league-high 2,715 yards in 2021, averaging 159 yards per game on the ground. The focus has shifted from the traditional running game that utilized the running back heavily to a forward-passing game dominated by wide receivers.Ī running game is still used heavily by some teams. Teams averaged 115.2 rushing yards per game in 2021, well below what we were used to seeing in the late 1980s. The NFL isn’t quite the rushing league it used to be. Video Poker Guide: Play the Best Online Video Poker Games. ![]() Thankfully, digital impressions work completely differently & cut the time it takes for each step of the process. This model acted as the base for any restorative designs (such as crowns or bridges) that you may have needed, or as a basis for designing your orthodontic treatment.Īs you might imagine, this process of taking a physical mold & having it prepared by a lab technician, who then sends back the designs, is all very time consuming, taking days or even weeks, depending on how busy the lab is. ![]() There, a lab technician made a stone model of your mouth by pouring ceramic into the mold. Because we can see the 3-D model of your mouth immediately, we’ll know right away if any section of it doesn’t look right, & we can re-scan you quickly right away, without having to ask you to come back in later as with traditional impressions.įor traditional impressions, once the impression goop set, the tray was removed & sent to a dental laboratory. Dental impressions are routine procedure in everyday dentistry to make crowns, bridges, fixed and removable dentures, splints, inlays. The accuracy of digital impressions is equivalent to traditional impressions & evidence suggests it may be even more accurate. Digital impressions allow dentists to gather all the information they need about your mouth to create your crown, bridge, retainer, or other dental appliance or treatment. Digital impressions can also be used for planning & visualizing how to straighten teeth, especially with systems that already include a digital workflows, such as clear aligners like Invisalign ®.ĭigital Impressions vs. Digital impressions can also be used in dental implant procedures, both for planning implant placement & to create a surgical guide that ensures accurate placement of implants on the day of the operation. ![]() We love that digital impressions give our patients an opportunity to see in detail what’s going on in their own mouths.ĭigital impressions are used in restorative dentistry to create tooth replacements, such as crowns, bridges & partial dentures. The images of your mouth can be viewed on a computer screen within seconds, to be viewed by both you & the dentist. We take the scan by systematically moving the wand around your mouth as it emits a specialized scanning light. It looks like the tool we use to polish your teeth, only bigger. The scanner is small enough that it fits on the end of a wand. You can select the topics that interest you from The Topic Menu. Sana Noor Siddiqui Share this with others: This page provides detailed and updated information about Digital impressions (Intraoral scan). Digital impressions are taken using an intraoral scanner that creates a detailed 3D image of your mouth. Digital impressions (Intraoral scan) by Dr. ![]() For example, every page sent to Japan is counted as two pages. HelloFax supports international faxing to over 70 countries, although some places may count as multiple pages. Either way, faxes are encrypted for added security and delivered via a convenient PDF. Other integrations include Dropbox, Box, OneDrive, and Evernote. ![]() Plans include unlimited secure storage for files that sync with The Cloud and add easy G Suite integration. HelloFax is a Dropbox company, which instantly speaks to its archiving and cloud support. Priority support reserved for business customersĬompatibility: Desktop | Google Drive | Dropbox | OneDrive | Evernote | Priceįax.Plus has five plans available for your fax services. Both Business and Enterprise plans allow you to manage and restrict user access for your employees, controlling areas like billing and account settings. In fact, you will need to upgrade to the Business or Enterprise plans in order to add multiple users or benefit from Slack and Zapier integrations. While you can send faxes, you cannot receive them, and there is no dedicated fax number. Fax.Plus does offer a free plan however, it is extremely restricted. You have the option to choose from smaller-volume plans, or you can sign up for an Enterprise plan that brings multiple fax numbers and unlimited users. Fax.Plus also boasts a leading server infrastructure with servers located in Switzerland. Upgraded security protocols include two-factor authentication with single sign-on (SSO) and TLS encryption. A free trial is available for 14 days.Ĭompatibility: Desktop | iOS | Android | Slack | Zapier | Google | Microsoft Word | Chrome Extension |įax.Plus has the ability to send faxes to more than 180 countries, using your own fax number or a new fax number from 47 available countries. PriceĮFax offers three plans based on your shipping volume with an additional set-up fee that accompanies all plans. If you hit any snags, eFax offers 24/7 customer service to help out. To protect sensitive and confidential documents, eFax offers Enhanced Security for its accounts, adding encryption and third-party hosting to ensure maximum security. With unlimited online storage, faxes and attachments are stored via popular cloud integrations like Dropbox, Google Drive, and iCloud, making them easily accessible for use in the future. You can bring your own fax number, or you can choose from local, toll-free, and international numbers. eFax will even save your signature to allow for easy signing. A free mobile app allows for easy faxing and viewing on the go. Multiple users may share the same account for simple use, and large file sharing is included, with faxing available for up to 20 recipients in a single fax. There is no fax machine or paper is required faxes are simply transmitted via your email, phone, or computer. CloseĬompatibility: Desktop | Android | iOS | EmailĮFax claims to be the world's #1 online fax service, and it is undoubtedly one of the most popular. If you see inaccuracies in our content, please report the mistake via this form. If we have made an error or published misleading information, we will correct or clarify the article. Our editors thoroughly review and fact-check every article to ensure that our content meets the highest standards. Our goal is to deliver the most accurate information and the most knowledgeable advice possible in order to help you make smarter buying decisions on tech gear and a wide array of products and services. ZDNET's editorial team writes on behalf of you, our reader. Indeed, we follow strict guidelines that ensure our editorial content is never influenced by advertisers. Neither ZDNET nor the author are compensated for these independent reviews. This helps support our work, but does not affect what we cover or how, and it does not affect the price you pay. When you click through from our site to a retailer and buy a product or service, we may earn affiliate commissions. And we pore over customer reviews to find out what matters to real people who already own and use the products and services we’re assessing. We gather data from the best available sources, including vendor and retailer listings as well as other relevant and independent reviews sites. ZDNET's recommendations are based on many hours of testing, research, and comparison shopping. ![]() ![]() wants to build enough trust with consumers and Lunar Toy Store will continue to focus on improving the consumer experience for users. If they are not satisfied they can apply for it immediately. Lunar Toy Store gives consumers a lot of autonomy and they can choose whether to keep the goods they have received. Lunar Toy Store's return policy provides convenience for customers who shop at. Now more and more People have become more cautious when shopping and the trust between consumers and merchants has become increasingly lost. If you can't return it smoothly it will be another unpleasant experience. 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I do not supply any support on these builds!īut I may answer questions here or on the freepascal mailinglist. The original unported source (version 9.45) is available from For a browser implemented using this component one can see fpbrowser. The ported code retains full compatibility with Delphi. To check if everything went to plan - provided the make didn't throw any errors -, you can start fp (just type fp in a terminal ) and check the revision number in the aboutbox. THtmlPort is a Lazarus/Free Pascal version of Dave Baldwin's HTML Components, including THtmlViewer, TFrameViewer and TFrameBrowser. You still have to create the two links above. This will give you a full installation in /usr/local. As of version 2.7.1, Free Pascal implemented basic ISO Pascal mode. Then delete fpcarm and samplecfg from /usr/local/bin and create the symlinks as explained above. Free Pascal Compiler (FPC) is a compiler for the closely related programming. Sudo make clean all distinstall OPT="-dREVINC -dFPC_ARMHF -CX -CpARMV6 -CfVFPV2 -CaEABIHF -OpARMV6 -O2 -OoFASTMATH -XX -Xs" after that, for future builds you need to just update the sources first time checkout the sources: svn checkout fpc first time install subverion: sudo apt-get install subversion Then make sure subversion is installed and checkout the sources from : If you want to compile it yourself, first download and install the full compiler as explained above. ![]() Just the textmode IDE (FP).īut they are cutting edge and fresh from the press. These releases are unofficial and they do not include Lazarus. When I have the time, I wil probably include this in a script and maybe even a distribution as a deb. that otherwise you would have to google and download and install. Sudo ln -sf /usr/local/lib/fpc/2.7.1/samplecfg /usr/local/bin/samplecfg 2012 the version Lazarus 1.1 - Fpc 2.7.1 (CodeTyphon 2.70) Os. Sudo ln -sf /usr/local/lib/fpc/2.7.1/ppcarm /usr/local/bin/ppcarm That would be /usr/local/bin, /usr/local/share and /usr/local/lib To install, delete any ppcarm and samplecfg from /usr/local/bin, extract the archive and copy the contained directories to /usr/local. in Python Basic Python for Java Developers How to Download YouTube Videos. You can obtain the sources with svn from . Given Number Python Program to Print Pascal Triangle NamedTuple in Python. ![]() There is a win32 to armhf standalone crosscompiler for those that need just that and there is a full package including all libraries that runs on the Raspberry Pi itself. The reason for that is that the official Freepascal distribution for Raspbian is many, many versions behind and trunk contains many, many language improvements and optimizations. ![]() I have decided to push daily builds for the latest and greatest version of the Freepascal compiler to |
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